Polyurethane on straightforward relief. Lower cost per square metre, high pour count, low handling risk. Cost per pour is typically the lowest of any moulding route on this kind of work.
Silicone on the same relief. Higher cost per square metre, similar or slightly higher pour count, similar handling risk. Cost per pour is higher than polyurethane. If the relief doesn't demand silicone, this is where you're overspending.
Polyurethane on fine detail. Lower initial cost, but with a shorter usable life because fine details wear or blur faster in polyurethane than silicone. Cost per pour looks decent early, then rises as replacements come sooner.
Silicone on fine detail. Higher initial cost, longer usable life on fine detail. Cost per pour is often lower over a full programme than polyurethane on the same detailed job — the maths flips.