It gets brushed on by hand, poured, poured under vacuum, pressed, or injected. Every concrete mould, formliner, GRC mould and cast stone tool we make comes out of one of those five routes, and for construction work the first two account for the great majority of it.
Printing, CNC machining and laser cutting come before all of that. They are how the pattern, the pattern plate and the backing frame get made. Useful, used daily, and not the product.
The rest of this page is the detail a precast yard manager or a conservation architect asks about on the phone. If you want the material side instead, that is on silicone and polyurethane mould materials for concrete.